The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Contact, Imprint, Acknowledgements

When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / C2H5O2 / Fenter(1993)_298K_210-290nm(resc)

DATAFILE: C2H5O2_Fenter(1993)_298K_210-290nm(resc).txt
NAME: ethylperoxy radical
FORMULA: C2H5O2
AUTHOR(YEAR): Fenter(1993)
T: 298K
λ: 210-290nm(resc)
BIBLIOGRAPHY: F.F. Fenter, V. Catoire, R. Lesclaux, and P.D. Lightfoot, "The ethylperoxy radical: Its ultraviolet spectrum, self-reaction, and reaction with HO2, each studied as a function of temperature", J. Phys. Chem. 97, 3530-3538 (1993); DOI: 10.1021/j100116a016
COMMENTS: Flash photolysis (Cl2/C2H6/O2/N2 mixtures)/UV absorption technique

The original data were rescaled to σ(240nm) = 4.24×10-18 cm2 molecule-1 recommended for CH3O2 by

G.S. Tyndall, R.A. Cox, C. Granier, R. Lesclaux, G.K. Moortgat, M.J. Pilling, A.R. Ravishankara, and T.J. Wallington, "The atmospheric chemistry of small organic peroxy radicals", J. Geophys. Res. D 106, 12157-12182 (2001)

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